Author

Abstract

The accepted kinetic theory forms a basis for modern thermodynamics and is mathematically based upon equipartition and degrees of freedom. It remains plagued with the necessity of numerous degrees of freedom exceptions for it to explain both empirically determined heat capacities and adiabatic indexes. Furthermore, assuming kT/2 per degree of freedom is to accept that a gas molecule possesses a specified energy without providing any clarity concerning that energy’s origins. Energy without an origin contravenes the first law of thermodynamics. This author’s previously published superior fit kinetic theory will be clarified and elaborated upon. This includes showing that this revised kinetic theory is a superior fit to both known heat capacities and adiabatic indexes. Not only is it a superior fit that does not rely upon any exceptions, this author’s kinetic theory also provides insight into the actual sources of a gas molecule’s energy. Furthermore, clarity concerning the difference between isometric (isochoric) and isobaric heat capacities in terms of sensible work will be discussed, along withits likely empirical verification.

Keywords

Adiabatic Index, Kinetic Theory, Degrees of Freedom, Heat Capacity